SeamStitch Polyurethane Caulk SDS

Safety Data Sheet

I. IDENTIFICATION

PRODUCT IDENTIFICATION
SeamStitch Polyurethane Caulk
Packaging:
CAS Number: n/a
DATE UPDATED
Thursday, May 10, 2018
EMERGENCY TELEPHONE NUMBER

800-535-5053

SUPPLIER INFORMATION

II. HAZARDS(S) IDENTIFICATION

  • Classification of the substance or mixture
  • Acute Tox. 4;H332 Harmful if inhaled
  • Skin Irrit. 2;H315 Causes skin irritation.
  • Eye Irrit. 2;H319 Causes serious eye irritation
  • Skin Sens. 1;H317 May cause an allergic skin reaction
  • Resp. Sens. 1;H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled.
  • Carc. 2;H351 Suspected of causing cancer.
  • STOT SE 3;H335 May cause respiratory irritation.
  • STOT RE 2;H373 May cause damage to organs through prolonged or repeated exposure. Specific Target Organs: ( hearing organs)
  • Flam. Liq. 2;H225 Highly Flammable liquid and vapor
Hazard Pictograms
  • Harmful
    Harmful
  • Flammable
    Flammable
  • Health Hazard
    Health Hazard
  • Toxic
    Toxic
  • H315 Causes skin irritation.
  • H317 May cause an allergic skin reaction
  • H319 Causes serious eye irritation.
  • H332 Harmful if inhaled.
  • H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled.
  • H335 May cause respiratory irritation.
  • H351 Suspected of causing cancer.
  • H373 May cause damage to organs through prolonged or repeated exposure.
  • [Prevention]:
  • P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking.
  • P201 Obtain special instructions before use.
  • P202 Do not handle until all safety precautions have been read and understood.
  • P261 Avoid breathing dust / fume / gas / mist / vapors / spray.
  • P264 Wash thoroughly after handling.
  • P271 Use only outdoors or in a well-ventilated area.
  • P272 Contaminated work clothing should not be allowed out of the workplace.
  • P280 Wear protective gloves / eye protection / face protection.
  • [Response]:
  • P302+352 IF ON SKIN: Wash with plenty of soap and water
  • P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell.
  • P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
  • P308+313 IF exposed or concerned: Get medical advice / attention.
  • P314 Get Medical advice / attention if you feel unwell.
  • P321 Specific treatment (see information on this label).
  • P333+313 If skin irritation or a rash occurs: Get medical advice / attention.
  • P337+313 If eye irritation persists: Get medical advice / attention.
  • P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  • P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
  • P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor / physician
  • P362 Take off contaminated clothing and wash before reuse.
  • P363 Wash contaminated clothing before reuse
  • [Storage]:
  • P403+233 Store in a well ventilated place. Keep container tightly closed
  • P405 Store locked up.
  • [Disposal]:
  • P501 Dispose of contents / container in accordance with local / national regulations.

III. COMPOSITION / INFORMATION ON INGREDIENTS

  • This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.
Ingredient/Chemical DesignationsWeight % GHS Classification Notes
Xylene CAS Number: 0001330-20-710 - 25Flam. Liq. 3;H226 Acute Tox. 4;H332 Acute Tox. 4;H312 Skin Irrit. 2;H315[1][2]
Oxirane, methyl-, polymer with 1,1'- methylenebis[isocyanatobenzene] CAS Number: 0157937-75-210 - 25Skin Irrit. 2;H315 Skin Sens. 1;H317 Eye Irrit. 2;H319 Acute Tox. 4;H332 Resp. Sens. 1;H334 STOT SE 3;H335 STOT RE 2;H373 Carc. 2;H351[1]
isocyanic acid, polymethylenepolyphenylene ester, polymer with .alpha.-hydro-.omega.- hydroxypolyoxy(methyl-1,2-ethanediy CAS Number: 0053862-89-81.0 - 10Skin Irrit. 2;H315 Skin Sens. 1;H317 Eye Irrit. 2;H319 Acute Tox. 4;H332 Resp. Sens. 1;H334 STOT SE 3;H335 STOT RE 2;H373[1]
Diphenylmethanediisocyanate CAS Number: 0000101-68-81.0 - 10Acute tox. 4;H332 STOT RE 2;H373 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Resp. Sens. 1;H334 Skin Sens. 1;H317[1][2]
Polymeric Diphenylmethane Diisocyanate CAS Number: 0009016-87-91.0 - 10Acute Tox. 4;H332 Skin Irrit. 2;H315 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Sens. 1;H317 Resp. Sens. 1;H334[1]
Benzene, 1-isocyanato-2-[(4-isocyanatophenyl)methyl]- CAS Number: 0005873-54-11.0 - 10Carc. 2;H351 Acute tox. 4;H332 STOT RE 2;H373 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Resp. Sens. 1;H334 Skin Sens. 1;H317[1]
Ethyl Benzene CAS Number: 0000100-41-41.0 - 10Flam. Liq. 2;H225 Acute Tox. 4;H332 STOT RE 2;H373 Asp. Tox. 1;H304[1][2]
Petroleum distillates, hydrotreated light CAS Number: 0064742-47-81.0 - 10Asp. Tox. 1;H304[1]
Tosyl isocyanate CAS Number: 0004083-64-10.10 - 1.0 Eye Irrit. 2;H319 STOT SE 3;H335 Skin Irrit. 2;H315 Resp. Sens. 1;H334[1]
  • In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.
  • [1] Substance classified with a health or environmental hazard.
  • [2] Substance with a workplace exposure limit.
  • [3] PBT-substance or vPvB-substance
  • *The full texts of the phrases are shown in Section 16.

IV. FIRST-AID MEASURES

  • General In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
  • Inhalation Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.
  • Eyes Flush with water initially and remove contact lenses. Continue to flush eyes with large amounts of water for 15 minutes. Get medical attention immediately.
  • Skin Remove contaminated clothing and shoes/boots. Wash affected area with large amounts of soap and water. Get medical attention immediately.
  • Ingestion If swallowed give two glasses of water to drink. Do not induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person.
  • Most important symptoms and effects, both acute and delayed
  • Overview Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 3 and Section 15 for each ingredient). Risk of cancer depends onduration and level of exposure.
  • Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.
  • Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritationand soreness with possible reversible damage. See section 2 for further details.
  • Inhalation Harmful if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms of breathing difficulties if inhaled.
  • Eyes Causes serious eye irritation.
  • Skin May cause an allergic skin reaction. Causes skin irritation.

V. FIRE-FIGHTING MEASURES

  • Extinguishing media
  • Water, carbon dioxide, foam or dry powder.
  • Special hazards arising from the substance or mixture
  • Hazardous decomposition: Will not occur if properly handled and stored.
  • Avoid breathing dust / fume / gas / mist / vapors / spray.
  • Advice for fire-fighters
  • Use water spray to cool non-involved containers.
  • Wear SCBA with full-face piece operating in a positive pressure demand mode and full protective gear.
  • This product is considered flammable and is a fire hazard. During a fire isocyanate vapors and other irritating gases may be generated by thermal decomposition or combustion. At temperatures above 400°F, polymeric MDI can polymerize and decompose which can cause pressure build-up in closed containers. Use cold water to cool fire exposed containers.
  • ERG Guide No.:  127

VI. ACCIDENTAL RELEASE MEASURES

  • Personal precautions, protective equipment and emergency procedures
  • Put on appropriate personal protective equipment (see section 8).
  • Environmental precautions
  • Do not allow spills to enter drains or waterways.
  • Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
  • Methods and material for containment and cleaning up
  • Shut off ignition sources including electrical equipment and flames. Contain spilled material. Absorb spills with inert material such as vermiculite, dry sand or earth. Place in a closed container but do not seal. Ventilate area to remove vapors.

VII. HANDLING AND STORAGE

  • Precautions for safe handling
  • Avoid prolonged or repeated skin contact. Avoid breathing aerosols, spray mists, and heated vapors. Use only in well ventilated area. Use good personal and industrial hygiene practices.
  • Keep container closed after each use.
  • See section 2 for further details. - [Prevention]:
  • Conditions for safe storage, including any incompatibilities
  • Handle containers carefully to prevent damage and spillage
  • Precautions should be taken to minimize exposure to atmospheric humidity or water as carbon dioxide may beformed which, in closed containers can result in pressurization. Care should be taken when re-opening partly used containers.
  • Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and electrical equipment are protected to the appropriate standard.
  • Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is used.
  • Examination of lung function should be carried out on a regular basis on persons applying this preparation.
  • Incompatible materials: Contact with water will cause this product to cure. Incompatible with acids, bases, and  oxidizers
  • Recommended storage range is less than 90°F
  • See section 2 for further details. - [Storage]:
  • Specific end use(s)
  • No data available.

VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters

Exposure

CAS No. IngredientSource Value
0000100-41-4Ethyl BenzeneOSHATWA 100 ppm (435 mg/m3)STEL 125 ppm
ACGIHTWA: 20 ppm2B, Revised 2011
NIOSHTWA 100 ppm (435 mg/m3) ST 125 ppm (545 mg/m3)
0000101-68-8Diphenylmethanediisocyanate OSHAC 0.2 mg/m3 (0.02 ppm)
ACGIHTWA: 0.005 ppm Ceiling: 0.01 ppmSkin, S
NIOSH TWA 0.05 mg/m3 (0.005 ppm) C 0.2 mg/m3 (0.020 ppm) [10- minute]
0001330-20-7 XyleneOSHASTEL 150 ppm
ACGIHTWA: 100 ppm STEL: 150 ppm
0005873-54-1Benzene, 1-isocyanato-2-[(4- isocyanatophenyl)methyl]-ACGIHTWA: 1.o mg/m3Revised 2008,
NIOSHTWA 10 mg/m3 (total) TWA 5 mg/m3 (resp)
0064742-47-8Petroleum distillates, hydrotreated light SupplierRecommended 300 ppm PEL
CAS No.IngredientSourceValue
0000100-41-4 Ethyl Benzene IARCGroup 2b: Yes
0000101-68-8DiphenylmethanediisocyanateIARCGroup 3: Yes
0001330-20-7 XyleneIARCGroup 3: Yes
0009016-87-9Polymeric Diphenylmethane DiisocyanateIARCGroup 3: Yes
0063449-39-8 Chlorinated paraffin c22-30 NTPSuspected: Yes
  • Exposure controls
  • Respiratory If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.
  • Eyes Chemical splash goggles (ANSI Z-87.1 or approved equivalent) and/or face shield. Have an eye wash station available.
  • Skin Avoid all skin contact by covering as much of the exposed skin area as possible with appropriate clothing. Wear impervious gloves
  • Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.
  • Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking orusing toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
  • See section 2 for further details. - [Prevention]:

IX. PHYSICAL AND CHEMICAL PROPERTIES

  • Appearance Viscous Liquid
  • Odor Not available
  • Odor threshold Not Measured
  • pH Not available
  • Melting point / freezing point Not applicable
  • Initial boiling point and boiling range 281 - 284°F
  • Flash Point 80°F
  • Evaporation rate (Ether = 1) Slower than ether
  • Flammability (solid, gas) Not Applicable
  • Upper/lower flammability or explosive limits Lower Explosive Limit: 1%, Upper Explosive Limit: 7%
  • Vapor pressure (Pa) Not established
  • Vapor Density Not available
  • Specific Gravity Not available
  • Specific Gravity Not available
  • Partition coefficient n-octanol/water (Log Kow) Not Measured
  • Auto-ignition temperature Not established
  • Decomposition temperature >400°F polymeric MDI can polymerize and decompose
  • Viscosity 20,000 - 40,000 cps
  • VOC Content 234 g/liter
  • Density 8 - 10 pounds per gallon
  • % Volatile 29 - 33% (by volume)
  • Other information
  • No other relevant information.

X. STABILITY AND REACTIVITY

  • Reactivity May polymerize
  • Chemical stability Stable under normal circumstances.
  • Possibility of hazardous reactions Reaction with water can create CO2.
  •  Conditions to avoid No data available
  • Incompatible materials
  • Contact with water will cause this product to cure. Incompatible with acids, bases, and oxidizers
  • Hazardous decomposition products
  • Will not occur if properly handled and stored.

XI. TOXICOLOGICAL INFORMATION

  • Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.
  • Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.
  • Based on the properties of the isocyanate content of this product, respiratory exposure may cause acute irritation and/or sensitization of the respiratory system resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to airborne concentrations ofisocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability.
IngredientOral LD50, mg/kgSkin LD50, mg/kgInhalation Vapor LC50, mg/L/4hrInhalation Dust/Mist LC50, mg/L/4hrInhalation Gas LC50, ppm
Polyoxypropylene glycol - (25322-69-4)2,000.00, Rat - Category: 4No data availableNo data availableNo data availableNo data available
Xylene - (1330-20-7)4,299.00, Rat - Category: 51,548.00, Rabbit - Category: 4No data available20.00, Rat - Category: NA5,000.00, Rat - Category: 4
Diphenylmethanediisocyanate - (101-68-8)4,700.00, Rat - Category: 5No data availableNo data availableNo data availableNo data available
Polymeric Diphenylmethane Diisocyanate - (9016-87-9) 49,000.00, Rat - Category: NA9,400.00, Rabbit - Category: NANo data availableNo data availableNo data available
Ethyl Benzene - (100-41-4)3,500.00, Rat - Category: 515,433.00, Rabbit - Category: NA17.20, Rat - Category: 4No data available4,000.00, Rat - Category: NA
Petroleum distillates, hydrotreated light - (64742-47-8)> 5,000.00, Rat - Category: NA>2,000.00, Rabbit - Category: 5No data availableNo data availableNo data available
  • Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).

XII. ECOLOGICAL INFORMATION

Toxicity

See Section 3 for chemical specific data.
Ingredient96 hr LC50 fish, mg/l48 hr EC50 crustacea, mg/lErC50 algae, mg/l
polyoxypropylene glycol - (25322-69-4)polyoxypropylene glycol - (25322-69-4)Not AvailableNot Available
Xylene - (1330-20-7)3.30, Oncorhynchus mykiss8.50, Palaemonetes pugio100.00 (72 hr), Chlorococcales
Diphenylmethanediisocyanate - (101-68-8Not Available 129.70, Daphnia magna Not Available
Chlorinated paraffin c22-30 - (63449-39-8300.00, Lepomis macrochirus102.00, Daphnia magnaNot Available
Ethyl Benzene - (100-41-4)4.20, Oncorhynchus mykiss2.93, Daphnia magna3.60 (96 hr), Pseudokirchneriella subcapitata
Petroleum distillates, hydrotreated light - (64742-47-8)45.00, Pimephales promelas4,720.00, Dendronereides heteropodaNot Available
  • Persistence and degradability
  • There is no data available on the preparation itself.
  • Bioaccumulative potential
  • Not Measured
  • Mobility in soil
  • No data available
  • Results of PBT and vPvB assessment
  • This product contains no PBT/vPvB chemicals
  • Other adverse effects
  • An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Potentially toxic to aquatic life.

XIII. DISPOSAL CONSIDERATIONS

  • Waste treatment methods
  • Observe all federal, state and local regulations when disposing of this substance.

XIV. TRANSPORT INFORMATION

DOT (Domestic Surface Transportation)IMO / IMDG (Ocean Transportation)ICAO/IATA
UN numberUN1263UN1263UN1263
UN proper shipping nameUN1263, Paint, 3, IIIPaintPaint
Transport hazard class(es)DOT Hazard Class: 3 IMDG: 3 Sub Class: Not ApplicableAir Class: 3
Air Class: 3IIIIIIIII
. Environmental hazards
Marine Pollutant: No
Special precautions for user
No further information

XV. REGULATORY INFORMATION

  • Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected egulations are represented.
  • Toxic Substance Control Act(TSCA) All components of this material are either listed or exempt from listing on the TSCA Inventory.
  • WHMIS Classification D2A
  • US EPA Tier II Hazards 
  • Fire: Yes
  • Sudden Release of Pressure: No
  • Reactive: No
  • Immediate (Acute): Yes
  • Delayed (Chronic): Yes
  • EPCRA 311/312 Chemicals and RQs (lbs):
  • Diphenylmethanediisocyanate ( 5,000.00)
  • Ethyl Benzene ( 1,000.00)
  • Xylene ( 100.00)
  • EPCRA 302 Extremely Hazardous:
  • To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • SARA 313
  • Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of FederalRegulations, Part 372:
Chemical NameCAS-NoWeight % SARA 313 - Threshold Values %
Xylene1330-20-710 - 301.0
Ethyl benzene100-41-47 - 130.1
Supplier Trade Secret5 - 10 1.0
Methylene bisphenyl isocyanate (MDI)101-68-8 1 - 51.0
  • SARA 311/312 Hazard Categories
  • Acute Health Hazard Yes
  • Chronic Health Hazard Yes
  • Fire Hazard Yes
  • Sudden Release of Pressure Hazard No
  • Reactive Hazard No
  • CWA (Clean Water Act)
  • This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):
Chemical NameCWA - Reportable QuantitiesCWA - Toxic PollutantsCWA - Priority PollutantsCWA - Hazardous Substances
Xylene 1330-20-7100 lbX
Ethyl benzene 100-41-41000lbsXXX
  • CERCLA
  • This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):
Chemical NameHazardous Substances RQsExtremely Hazardous Substances RQsRQ
Xylene 1330-20-7100 lbRQ= 100 lb final RQ RQ= 45.4 kg final RQ
Ethyl benzene 100-41-41000 lbRQ 1000 lb final RQ RQ 454 kg final RQ
Methylene bisphenyl isocyanate (MDI) 101-68-85000 lbRQ 5000 lb final RQ RQ 2270 kg final RQ
  • US State Regulations
  • California Proposition 65
  • This product contains the following Proposition 65 chemicals:
Chemical NameCalifornia Prop. 65
Ethyl benzene - 100-41-4 Carcinogen
  • New Jersey RTK Substances (>1%):
  • Aluminum (Al),  Diphenylmethanediisocyanate, Ethyl Benzene, Polymeric  Diphenylmethane, Diisocyanate, Xylene
  • Pennsylvania RTK Substances (>1%):
  • Aluminum (Al), Diphenylmethanediisocyanate, Ethyl Benzene, Xylene
Chemical NameNew JerseyMassachusettsPennsylvaniaRhode IslandIllinois
Xylene 1330-20-7XXXXX
Ethyl benzene 100-41-4XXXXX
Supplier Trade SecretXXXX
Polymethylene polyphenylene isocyanate 9016-87-9XX
XXXXX
Methylene bisphenyl isocyanate (MDI) 101-68-8
  • International Regulations
  • Mexico National occupational exposure limits
ComponentExposure Limits
Xylene 1330-20-7 ( 10 - 30 )Mexico: TWA= 100 ppm Mexico: TWA= 435 mg/m3 Mexico: STEL= 150 ppm Mexico: STEL= 655 mg/m3
Ethyl benzene 100-41-4 ( 7 - 13 )Mexico: TWA 100 ppm Mexico: TWA 435 mg/m3 Mexico: STEL 125 ppm Mexico: STEL 545 mg/m3
Supplier Trade Secret ( 5 - 10 )Mexico: TWA= 10 mg/m3
Methylene bisphenyl isocyanate (MDI) 101-68-8 ( 1 - 5 )Mexico: TWA 0.02 ppm Mexico: TWA 0.2 mg/m3 Mexico: TWA 0.005 ppm Mexico: TWA 0.051 mg/m3
  • Canada WHMIS Hazard Class
  • D2A - Very toxic materials
  • D2B - Toxic materials
  • B2 - Flammable liquid

XVI. OTHER INFORMATION

This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.