EnergyMax Aliphatic Polyurethane SDS

Safety Data Sheet

I. IDENTIFICATION

PRODUCT IDENTIFICATION
EnergyMax Aliphatic Polyurethane
Packaging: Pail, Drum
CAS Number: n/a
DATE UPDATED
Thursday, May 10, 2018
EMERGENCY TELEPHONE NUMBER
INFOTRAC: 800-535-5053
SUPPLIER INFORMATION

II. HAZARDS(S) IDENTIFICATION

Classification of the substance or mixture
Acute Tox. 4;H332 Harmful if inhaled.
Skin Irrit. 3;H316 Causes mild skin irritation. (Not adopted by US OSHA)
Eye Irrit. 2;H319 Causes serious eye irritation.
Skin Sens. 1;H317 May cause an allergic skin reaction.
Resp. Sens. 1;H334 May cause allergy or asthma symptoms of breathing difficulties if inhaled.
Repr. 2;H361 Suspected of damaging fertility or the unborn child.
STOT RE 2;H373 May cause damage to organs through prolonged or repeated exposure. Specific Target Organs: ( hearing organs)
Aspir. 1; H304 May be fatal if swallowed and enters airways.
Flam. Liq. 3;H225 Highly Flammable liquid and vapor.
Label Elements
Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.
Hazard Pictograms
  • Harmful
    Harmful
  • Flammable
    Flammable
  • Health Hazard
    Health Hazard
H225 Highly flammable liquid and vapor.
H316 Causes mild skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergic or asthmatic symptoms or breathing difficulties if inhaled.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
[Prevention]:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust / fume / gas / mist / vapors / spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
[Responce]:
P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P304+312 IF INHALED: Call a POISON CENTER or doctor / physician if you feel unwell.
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P308+313 IF exposed or concerned: Get medical advice / attention.
P314 Get Medical advice / attention if you feel unwell.
P321 Specific treatment (see information on this label).
P331 Do NOT induce vomiting.
P333+313 If skin irritation or a rash occurs: Get medical advice / attention.
P337+313 If eye irritation persists: Get medical advice / attention.
P340 Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342+311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor / physician.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
[Storage]:
P405 Store locked up.
[Disposal]:
P501 Dispose of contents / container in accordance with local / national regulations.

III. COMPOSITION / INFORMATION ON INGREDIENTS

Ingredient/Chemical Designations Weight% GHS Classification Notes
Polyoxypropylene glycol CAS Number: 0025322-69-4 25-50 Not Classified [1]
Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3- trimethyl- CAS Number: 0004098-71-9 10-25 Acute Tox. 3;H331
Eye Irrit. 2;H319
STOT SE 3;H335
Skin Irrit. 2;H315
Resp. Sens. 1;H334
Skin Sens. 1;H317
Aquatic Chronic 2;H411
[1][2]
Titanium dioxide CAS Number: 0013463-67-7
10-25 Not Classified [1][2]
Aliphatic Hydrocarbon CAS Number: 0064742-49-0
10-25 Asp. Tox. 1;H304 [1]
HDI Homopolymer CAS Number: 0028182-81-2
10-25 Skin Sens. 1;H317
Resp. Sens. 1;H334
[1]
Xylene CAS Number: 0001330-20-7 1.0-10 Flam. Liq. 3;H226
Acute Tox. 4;H332
Acute Tox. 4;H312
Skin Irrit. 2;H315
[1][2]
Ethyl Benzene CAS Number: 0000100-41-4 1.0-10 Flam. Liq. 2;H225
Acute Tox. 4;H332
STOT RE 2;H373
Asp. Tox. 1;H304
[1][2]
Fatty Acid Amide CAS Number: Proprietary 1.0-10 Aquatic Chronic 2;H411 [1]
Tosyl isocyanate CAS Number: 0004083-64-1 0.10-1.0 Eye Irrit. 2;H319
STOT SE 3;H335
Skin Irrit. 2;H315
Resp. Sens. 1;H334
[1]
Dimethyltindineodeconoate CAS Number: 0068928-76-7 0.10-1.0 Acute Tox. 4;H302
Repr. 2;H361
STOT RE 1;H372
[1]
2-N-octyl-4-isothiazoline-3-one CAS Number: 0026530-20-1 0.10-1.0 Acute Tox. 3;H331
Acute Tox. 3;H311
Acute Tox. 4;H302
Skin Corr. 1B;H314
Skin Sens. 1;H317 (@>0.05%)
Aquatic Acute 1;H400
Aquatic Chronic 1;H410
[1]
1,6-Hexamethylene Diisocyanate CAS Number: 0000822-06-0 0.10-1.0 Acute Tox. 3;H331
Eye Irrit. 2;H319
STOT SE 3;H335
Skin Irrit. 2;H315
Resp. Sens. 1;H334
Skin Sens. 1;H317
[1][2]
In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit.
*The full texts of the phrases are shown in Section 16.

IV. FIRST-AID MEASURES

Description of first aid measures
General
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
Inhalation
Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.
Eyes
Get medical attention immediately.
Skin
Remove contaminated clothing and shoes/boots. Wash affected area with alcohol. Don’t wash with water.
Ingestion
If swallowed obtain immediate medical attention. Keep at rest. Do NOT induce vomiting
Most important symptoms and effects, both acute and delayed
Overview
Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage. See section 2 for further details.
Inhalation
Harmful in inhaled. May cause allergy or asthma symptoms of breathing difficulties if inhaled.
Eyes
Causes serious eye irritation.
Skin
May cause an allergic skin reaction. Causes mild skin irritation. (Not adopted by US OSHA)

V. FIRE-FIGHTING MEASURES

Extinguishing media
Water, carbon dioxide, foam or dry powder.
Special hazards arising from the substance or mixture
Hazardous decomposition: Reaction with water can create CO2.
Avoid breathing dust / fume / gas / mist / vapors / spray.
Do not get in eyes, on skin, or on clothing.
Advice for fire-fighters
Use water spray to cool non-involved containers. Wear SCBA with full-face piece operating in a positive pressure demand mode and full protective gear. This product is considered combustible and is a fire hazard. During a fire isocyanate vapors and other irritating gases may be generated by thermal decomposition or combustion. At temperatures above 137°F it can cause pressure build-up in closed containers. Use cold water to cool fire-exposed containers.
ERG Guide No. 127

VI. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Put on appropriate personal protective equipment (see section 8).
Environmental precautions
Do not allow spills to enter drains or waterways.
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
Methods and material for containment and cleaning up
Ventilate the area and avoid breathing vapors. Take the personal protective measures listed in section 8. Contain and absorb spillage with non-combustible materials e.g. sand, earth, vermiculite. Place in a suitable container. The contaminated area should be cleaned up immediately with a suitable decontaminant. One possible (flammable) decontaminant comprises (by volume): water (45 parts), ethanol or isopropyl alcohol (50 parts), concentrated (d:0,880) ammonia solution (5 parts). A non-flammable alternative is sodium carbonate (5 parts), water (95 parts). Add the same decontaminant to any residues and allow to stand for several days in a non-sealed container until no further reaction occurs. Once this stage is reached, close container and dispose of in accordance with the waste regulations (see section 13). Do not allow spills to enter drains or watercourses. If drains or sewers are contaminated, inform the local water company immediately. In the case of contamination of rivers, streams or lakes the Environmental Protection Agency should also be informed.

VII. HANDLING AND STORAGE

Precautions for safe handling
Avoid prolonged or repeated skin contact. Avoid breathing aerosols, spray mists, and heated vapors. Use only in well ventilated area. Use good personal and industrial hygiene practices.
See section 2 for further details. - [Prevention]:
Conditions for safe storage, including any incompatibilities
Handle containers carefully to prevent damage and spillage.

Precautions should be taken to minimize exposure to atmospheric humidity or water as carbon dioxide may be formed which, in closed containers can result in pressurization. Care should be taken when re-opening partly used containers.

Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and electrical equipment are protected to the appropriate standard.

Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is used.

Examination of lung function should be carried out on a regular basis on persons applying this preparation.
Incompatible materials: Contact with water will cause this product to cure. Incompatible with acids, bases, and oxidizers

Recommended storage range is less than 90°F.
See section 2 for further details. - [Storage]:
Specific end use(s)
No data available.

VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters
No data available
CAS No. Ingredient Source Value
0000100-41-4
1-4 Ethyl Benzene OSHA
ACGIH
NIOSH
TWA 100 ppm (435 mg/m3 )STEL 125 ppm
TWA: 20 ppm2B, Revised 2011,
TWA 100 ppm (435 mg/m3 ) ST 125 ppm (545 mg/m3 )
0000822-06-0
1,6-Hexamethylene Diisocyanate ACGIH
NIOSH
TWA: 0.005 ppm Ceiling: 0.01 ppmS
TWA 0.005 ppm (0.035 mg/m3 ) C 0.020 ppm (0.140 mg/m3 ) [10- minute]
0001330-20-7
Xylene OSHA
ACGIH
STEL 150 ppm
TWA: 100 ppm STEL: 150 ppm
0004098-71-9 Cyclohexane, 5-isocyanato-1- (isocyanatomethyl)-1,3,3-trimethyl ACGIH
NIOSH
TWA: 0.005 ppm Ceiling: 0.01 ppmS
TWA 0.005 ppm (0.045 mg/m3 ) ST 0.02 ppm (0.180 mg/m3 ) [skin]
Exposure controls
Respiratory
When concentrations exceed the exposure limits shown above workers must wear appropriate respirators approved in accordance with Directive 89/656/EEC and the Personal Protection Equipment Regulations. Provision of other controls such as exhaust ventilation should be considered if practical.
An air fed respirator must be worn when applying this product in a confined space. Even in open spaces, an air fed respirator should be worn when spraying. If applying by brush or roller in an open, well ventilated area, air fed respirators could be replaced by a charcoal filter mask.
Eyes
Chemical splash goggles (ANSI Z-87.1 or approved equivalent) and/or face shield. Have an eye wash station available.
Skin
Avoid all skin contact by covering as much of the exposed skin area as possible with appropriate clothing. Wear impervious gloves.
Engineering Controls
Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.
Provide adequate ventilation. This should be achieved by the use of local exhaust ventilation and good general extraction. Air-fed protective respiratory equipment must be worn by spray operators even when good ventilation is provided. In other operations, if local exhaust ventilation and good general extraction are not sufficient to maintain concentrations of particulates and solvent vapor below the WEL, suitable respiratory protection must be worn. (See Personal Protection)
Persons with a history of asthma, allergies, chronic or recurrent respiratory disease should not be employed in any process in which this preparation is used.
Examination of lung function should be carried out on a regular basis on persons spraying this preparation.
Other Work Practices
Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
See section 2 for further details. - [Prevention]:

IX. PHYSICAL AND CHEMICAL PROPERTIES

Appearance Viscous Liquid
Odor Not specified
Odor threshold Not determined
pH Not available
Melting point / freezing point 281 - 284°F
Flash Point 80°F
Evaporation rate (Ether = 1) Slower than ether
Flammability (solid, gas) Not Applicable
Upper/lower flammability or explosive limits Lower Explosive Limit: 1% Upper Explosive Limit: 7%
Vapor pressure (Pa) Not established
Vapor Density Not available
Specific Gravity Not available
Solubility in Water Nil, reacts with water
Partition coefficient n-octanol/water (Log Kow) Not Measured
Auto-ignition temperature Not established
Decomposition temperature Not available
Viscosity (cSt) 2,000 - 40,000 cps
VOC Content < 250 g/liter
Density 8 - 11 pounds per gallon
% Volatile < 26% (by volume)
Other Information
No other relevant information

X. STABILITY AND REACTIVITY

Reactivity
May polymerize if mixed with water.
Chemical stability
Stable under recommended storage and handling conditions (see section 7). In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide, oxides of nitrogen, hydrogen cyanide may be produced.
Keep away from oxidizing agents, strongly alkaline and strongly acid materials, amines, alcohols and water.Uncontrolled exothermic reactions occur with amines and alcohols. The product reacts slowly with water resulting in evolution of carbon dioxide. In closed containers, pressure build up could result in distortion, blowing, and in extreme cases, bursting of the container
Possibility of hazardous reactions
No data available.
Conditions to avoid
Excessive heat and open flame.
Incompatible materials
Contact with water will cause this product to cure. Incompatible with acids, bases, and oxidizers
Hazardous decomposition products
Reaction with water can create CO2

XI. TOXICOLOGICAL INFORMATION

Acute toxicity
Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.
Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.
Based on the properties of the isocyanate content of this product, respiratory exposure may cause acute irritation and/or sensitization of the respiratory system resulting in asthmatic symptoms, wheezing and a tightness of the chest. Sensitized persons may subsequently show asthmatic symptoms when exposed to airborne concentrations of isocyanates well below the occupational exposure limit. Repeated exposure may lead to permanent respiratory disability.

Ingredient Oral LD50, mg/kg Skin LD50, mg/kg Inhalation Vapor LC50, mg/L/4hr Inhalation Dust/Mist LC50, mg/L/4hr Inhalation Gas LC50, ppm
Polyoxypropylene glycol - (25322-69-4) 2,000.00, Rat - Category: 4 No data available No data available No data available No data available
Xylene - (1330-20-7) 4,299.00, Rat - Category: 5 1,548.00, Rabbit - Category: 4 No data available 20.00, Rat - Category: NA 5,000.00, Rat - Category: 4
Ethyl Benzene - (100-41-4) 3,500.00, Rat - Category: 5 15,433.00, Rabbit - Category: NA 17.20, Rat - Category: 4 No data available 4,000.00, Rat - Category: NA
2-N-octyl-4-isothiazoline-3-one - (26530-20-1) 550.00, Rat - Category: 4 690.00, Rabbit - Category: 3 No data available 0.27, Rat - Category: 2 No data available
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).

Carcinogen Data

CAS No. Ingredient Source Value
0000100-41-4 Ethyl Benzene IARC Group 2b: Yes
0001330-20-7 Xylene IARC Group 3: Yes
0013463-67-7 Titanium dioxide IARC Group 2b: Yes

XII. ECOLOGICAL INFORMATION

Toxicity
Toxicity Toxic to aquatic life with long lasting effects.
No additional information provided for this product. See Section 3 for chemical specific data.
Aquatic Ecotoxicity

Ingredient 96 hr LC50 fish, mg/l 48 hr EC50 crustacea, mg/l ErC50 algae, mg/l
Polyoxypropylene glycol - (25322-69-4) 650.00, Menidia beryllina N/A N/A
Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3- trimethyl- - (4098-71-9) 4.00, Chaetogammarus marinus 83.70, Daphnia magna 118.70 (72 hr), Scenedesmus subspicatus
Aliphatic Hydrocarbon - (64742-49-0) N/A 2.60, Chaetogammarus marinus N/A
HDI Homopolymer - (28182-81-2) 100.00, Danio rerio 100.00, Daphnia magna 100.00 (72 hr), Scenedesmus subspicatus
Xylene - (1330-20-7) 3.30, Oncorhynchus mykiss 8.50, Palaemonetes pugio 100.00 (72 hr), Chlorococcales
Ethyl Benzene - (100-41-4) 4.20, Oncorhynchus mykiss 2.93, Daphnia magna 3.60 (96 hr), Pseudokirchneriella subcapitata
2-N-octyl-4-isothiazoline-3-one - (26530-20-1) 0.0555, Oncorhynchus mykiss 0.18, Daphnia magna 0.084 (72 hr), Scenedesmus subspicatus
1,6-Hexamethylene Diisocyanate - (822-06-0) 82.80, Danio rerio √ 89.10, Daphnia magna a 77.40 (72 hr), Desmodesmus subspicatus
Persistence and degradability
There is no data available on the preparation itself.
Bioaccumulative potential
Not Measured
Mobility in soil
No data available.
Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.
Other adverse effects
No data available.

XIII. DISPOSAL CONSIDERATIONS

Waste treatment methods
Observe all federal, state and local regulations when disposing of this substance.

XIV. TRANSPORT INFORMATION

DOT (Domestic Surface Transportation) IMO / IMDG (Ocean Transportation) ICAO/IATA
UN number UN1263 UN1263 UN1263
UN proper shipping name UN1263, Paint, 3, III Paint Paint
Transport hazard class(es) DOT Hazard Class: 3 IMDG: 3
Sub Class: Not Applicable
Air Class: 3
Packing group III III III
Enviromental hazards
IMDG
Marine Pollutant: Yes(Aliphatic Hydrocarbon )
Special precautions for user
No further information

XV. REGULATORY INFORMATION

Regulatory Overview
The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented.
Toxic Substance Control Act ( TSCA)
All components of this material are either listed or exempt from listing on the TSCA Inventory.
WHMIS Classification
D2A
US EPA Tier II Hazards
Fire: No
Sudden Release of Pressure: No
Reactive: No
Immediate (Acute): Yes
Delayed (Chronic): Yes
EPCRA 311/312 Chemicals and RQs (lbs):
Ethyl Benzene ( 1,000.00)
Xylene ( 100.00)
EPCRA 302 Extremely Hazardous:
Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl
EPCRA 313 Toxic Chemicals:
1,6-Hexamethylene Diisocyanate
Ethyl Benzene
Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl
Xylene
Proposition 65 - Carcinogens (>0.0%):
Ethyl Benzene
Titanium dioxide
New Jersey RTK Substances (>1%):
Ethyl Benzene
Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl
Titanium dioxide
Xylene
Pennsylvania RTK Substances (>1%):
Ethyl Benzene
Cyclohexane, 5-isocyanato-1-(isocyanatomethyl)-1,3,3-trimethyl
Titanium dioxide
Xylene

XVI. OTHER INFORMATION

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.

This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.

Judgments as to the suitability of information herein for the purchaser’s purposes are necessarily the purchaser’s responsibility. Although reasonable care has been taken in the preparation of such information, Aldo Products Company, extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to the purchaser’s intended purpose or for consequences of its use.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.