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- PRODUCT IDENTIFICATION
- SeamStitch Silicone Caulk
- Packaging: pails
- CAS Number: n/a
- DATE UPDATED: Thursday, May 10, 2018
- EMERGENCY TELEPHONE NUMBER: INFOTRAC: 800-535-5053
II. HAZARDS(S) IDENTIFICATION
- Flam. Liq. 4;H226: Combustible liquid.
- Skin Irrit. 3;H316: Causes mild skin irritation. (Not adopted by US OSHA)
- Eye Irrit. 2;H319: Causes serious eye irritation.
- Skin Sens. 1;H317: May cause an allergic skin reaction.
- Carc. 2;H351: Suspected of causing cancer.
- Repr. 2;H361F: Suspected of damaging fertility.
III. COMPOSITION / INFORMATION ON INGREDIENTS
|Ingredient/Chemical Designations||Weight %||GHS Classification||Notes|
|Dimethylsiloxane - CAS Number: 0063148-62-9||1.0 - 10||Aquatic Chronic 2;H411|||
|Methyltris(methylethylketoximino)silane CAS Number: 0022984-54-9||1.0 - 10||Eye Irrit. 2;H319 Skin Irrit. 2;H315 Skin Sens. 1;H317|||
|Titanium dioxide - CAS Number: 0013463-67-7||1.0 - 10||Not Classified|| |
|2-Butanone oxime - CAS Number: 0000096-29-7||1.0 - 10||Carc. 2;H351 Acute Tox. 4;H312 Eye Dam. 1;H318 Skin Sens. 1;H317|| |
|Proprietary*||0.10 - 1.0||Skin Irrit. 2;H315, Eye Irrit. 2;H319, Skin Sens. 1;H317 , Aquatic Chronic 3;H412|| |
|Cyclotetrasiloxane, octamethyl- CAS Number: 0000556-67-2||0.10 - 1.0||Repr. 2;H361f, Aquatic Chronic 4;H413|| |
*In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. Substance classified with a health or environmental hazard. Substance with a workplace exposure limit. PBT-substance or vPvB-substance.*The full texts of the phrases are shown in Section 16.
IV. FIRST-AID MEASURES
- GENERAL: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
- EYE CONTACT: Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention.
- SKIN CONTACT: Remove contaminated clothing. Wash affected area with large amounts of soap and water or used a recognized skin cleanser.
- INHALATION: Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious, place in recovery position and seek immediate attention.
- INGESTION: If swallowed, obtain immediate medical attention. Do NOT induce vomiting.
Overview: Effects of Overexposure
- Inhalation: Nasal and respiratory irritation, dizziness, fatigue, unconsciousness, asphyxiation.
- Ingestion: Can cause gastrointestinal disorders.
- Skin: Possible irritation, dermatitis, and defatting.
- Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 3 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.See section 2 for further details.
- Eyes: Causes serious eye irritation.
- Skin: May cause an allergic skin reaction. Causes mild skin irritation.
V. FIRE-FIGHTING MEASURES
- EXTINGUISHING MEDIA: Water, carbon dioxide, foam or dry powder.
- SPECIAL HAZARDS ARISING FROMTHE SUBSTANCE OR MIXTURE:
Hazardous decomposition: High temperatures and fires may produce carbon monoxide, oxides of nitrogen and various hydrocarbon fragments.
- Keep away from heat / sparks / open flames / hot surfaces - No smoking. Keep cool.
- Ground / bond container and receiving equipment.
- Use explosion-proof electrical / ventilating / light / equipment.
- Use only non-sparking tools.
- Take precautionary measures against static discharge.
- Avoid breathing dust / fume / gas / mist / vapors / spray.
- ADVICE FOR FIRE-FIGHTERS:This product is considered combustible and is a fire hazard. It supports combustion and decomposes under fire conditions to give off toxic materials. Do not pour, spill, or store near heat, spark sources, or open flame.
- If electrical equipment is involved, the use of foam should be avoided. Use water spray to cool non-involved containers.
- Wear SCBA with a full-face piece operated in the positive pressure demand mode and full protective clothing (Bunker Gear) when fighting fires.
- PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Put on personal protective equipment.
- ENVIRONMENTAL PRECAUTIONS: Do not allow spills to enter drains and waterways.
- SPILL/LEAK PROCEDURE: Small spill: Remove with absorbent material. Large spill: Eliminate all ignition sources. Ventilate enclosed areas or wear self-contained breathing apparatus. Recover free liquid in closed containers. Keep out of sewers and water courses. Clean area with absorbent material.
VI. ACCIDENTAL RELEASE MEASURES
- Personal precautions, protective equipment and emergency procedures: Put on appropriate personal protective equipment (see section 8).
- Environmental precautions: Do not allow spills to enter drains or waterways.
- Methods and material for containment and cleaning up:
- Small spill: Remove with absorbent material.
- Large spill: Eliminate all ignition sources. Ventilate enclosed areas or wear self-contained breathing apparatus.
- Recover free liquid in closed containers. Keep out of sewers and water courses. Clean area with absorbent material.
VII. HANDLING AND STORAGE
- HANDLING PRECAUTIONS: Protect from freezing.
- CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
Handle containers carefully to prevent damage and spillage.
Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and electrical equipment are protected to the appropriate standard.
Avoid strong oxidizing agents, concentrated nitric and sulfuric acids, halogen, and molten sulfur.
Store in a cool, dry place. Keep container tightly closed when not in use.
See section 2 for further details.
VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION
- EXPOSURE: No volatile ingredients with exposure guidelines
- EXPOSURE CONTROLS RESPIRATORY: If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.
- RESPIRATORY: If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.
- EYES: Not normally required.
- SKIN: Use protective gloves as needed to avoid skin irritation.
- ENGINEERING CONTROLS: Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.
- OTHER WORK PRACTICES: Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
IX. PHYSICAL AND CHEMICAL PROPERTIES
|Appearance||Viscous white or gray Liquid|
|Odor threshold||Not determined|
|Melting point / freezing point||Not determined|
|Initial boiling point and boiling range||Not determined|
|Flash Point||160°F ASTM D93|
|Evaporation rate (Ether = 1)||Slower than ether|
|Flammability (solid, gas)||Not Applicable|
|Upper/lower flammability or explosive limits||Lower Explosive Limit: 1.1|
|Upper Explosive Limit: 5.0|
|Vapor pressure (Pa)||Not determined|
|Vapor Density||Not available|
|Specific Gravity||1.37 (H2O = 1)|
|Solubility in Water||Negligible|
|Partition coefficient n-octanol/water (Log Kow)||Not Measured|
|Auto-ignition temperature||Not available|
|Decomposition temperature||Not available|
|Viscosity (cSt)||Not available|
|VOC Content||< 50 g/liter|
|Density||Heavier than air (Air + 1)|
X. STABILITY AND REACTIVITY
- REACTIVITY: Hazardous Polymerization will not occur.
- CHEMICAL STABILITY: Stable under normal circumstances.
- POSSIBILITY OF HAZARDOUS REACTION: No data available.
- CONDITIONS TO AVOID: Keep away from heat, flame and other potential ignition sources.
- INCOMPATIBLE MATERIALS: Avoid strong oxidizing agents, concentrated nitric and sulfuric acids, halogen, and molten sulfur,
- HAZARDOUS DECOMPOSITION PRODUCTS: High temperatures and fires may produce carbon monoxide, oxides of nitrogen and various hydrocarbon fragments.
XI. TOXICOLOGICAL INFORMATION
|Ingredient||Oral LD50, mg/kg||Skin LD50, mg/kg||Inhalation Vapor LC50, mg/L/4hr||Inhalation Dust/Mist LC50, mg/L/4hr||Inhalation Gas LC50, ppm|
|2-Butanone oxime - (96-29-7)||930.00, Rat - Category: 4||2,000.00, Rabbit - Category: 4||20.00, Rat - Category: 4||No data available||5,000.00, Rat - Category: 4|
|Cyclotetrasiloxane, octamethyl- - (556-67-2)||2,000.00, Rat - Category: 4||4,640.00, Rabbit - Category: 5||36.00, Rat - Category: NA||No data available||No data available|
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).
|0013463-67-7||Titanium dioxide||IARC||Group 2b: Yes|
XII. ECOLOGICAL INFORMATION
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and GHS and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 3 for details
|Ingredient||96 hr LC50 fish, mg/l||48 hr EC50 crustacea, mg/l||ErC50 algae, mg/l|
|Dimethylsiloxane - (63148-62-9)||3.16, Ictalurus punctatus||44.50, Daphnia magna||Not Available|
|2-Butanone oxime - (96-29-7)||320.00, Leuciscus idus||500.00, Daphnia magna||83.00 (72 hr), Scenedesmus subspicatus|
|Proprietary||597.00, Danio rerio||81.00, Daphnia magna||126.00 (72 hr), Scenedesmus subspicatus|
|Cyclotetrasiloxane, octamethyl- - (556-67-2)||200.00, Leuciscus idus||25.20, Daphnia magna||Not Available|
- PERSISTENCE AND DEGRADABILITY: There is no data available on the preparation itself.
- BIOACCUMULATIVE POTENTIAL: Not measured.
- MOBILITY IN SOIL: No data available.
- RESULTS OF PBT AND vPvB ASSESSMENT: This product contains PBT/vPvB chemicals.
- OTHER ADVERSE EFFECTS: An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Potentially toxic to aquatic life.
XIII. DISPOSAL CONSIDERATIONS
- WASTE TREATMENT METHODS: Observe all federal, state, and local regulations when disposing of this substance.
XIV. TRANSPORT INFORMATION
|DOT (Domestic Surface Transportation)||IMO / IMDG (Ocean Transportation)||ICAO/IATA|
|UN number||Not Applicable||Not Regulated||Not Regulated|
|UN proper shipping name||Not Regulated||Not Regulated||Not Regulated|
|Transport hazard class(es)||DOT Hazard Class: Not Applicable||IMDG: Not Applicable||Air Class: Not Applicable|
|Sub Class: Not Applicable|
|Packing group||Not Applicable||Not Applicable||Not Applicable|
|Environmental hazards IMDG||Marine Pollutant: No|
|Special precautions for user||No further information|
- PRODUCT LABEL: SeamStitch Silicone Caulk
- SHIPPING NAME: Not Applicable
- SHIPPING CLASS: Non Hazardous
XV. REGULATORY INFORMATION
- Regulatory Overview: The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented.
- Toxic Substance Control Act ( TSCA): All components of this material are either listed or exempt from listing on the TSCA Inventory.
- WHMIS Classification: B3 D2A
- US EPA Tier II Hazards: Fire: No Sudden Release of Pressure: No Reactive: No Immediate (Acute): Yes Delayed (Chronic): Yes
- EPCRA 311/312 Chemicals and RQs:To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- EPCRA 302 Extremely Hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- EPCRA 313 Toxic Chemicals: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- Proposition 65 - Carcinogens (>0.0%): Titanium dioxide
- Proposition 65 - Developmental Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- Proposition 65 - Male Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- New Jersey RTK Substances (>1%): Titanium dioxide
- Pennsylvania RTK Substances (>1%): Titanium dioxide
XVI. OTHER INFORMATION
The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.