SeamStitch Butyl Caulk SDS

Safety Data Sheet

I. IDENTIFICATION

PRODUCT IDENTIFICATION
SeamStitch Butyl Caulk
Packaging:
CAS Number: n/a
DATE UPDATED
Thursday, May 10, 2018
EMERGENCY TELEPHONE NUMBER

800-535-5053

SUPPLIER INFORMATION

II. HAZARDS(S) IDENTIFICATION

  • Flam. Liq. 2;H225 Highly Flammable liquid and vapor.
  • Skin Irrit. 2;H315 Causes skin irritation.
  • Eye Irrit. 2;H319 Causes serious eye irritation.
  • Skin Sens. 1;H317 May cause an allergic skin reaction.
  • Aspir. 1; H304 May be fatal if swallowed and enters airways.
Hazard Pictograms
  • Harmful
    Harmful
  • Flammable
    Flammable
  • Health Hazard
    Health Hazard
  • H315 Causes skin irritation.
  • H225 Highly flammable liquid and vapor.
  • H317 May cause an allergic skin reaction
  • H319 Causes serious eye irritation.
  • [PREVENTION]:
  • P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking.
  • P235 Keep cool.
  • P240 Ground / bond container and receiving equipment.
  • P241 Use explosion-proof electrical / ventilating / light / equipment.
  • P242 Use only non-sparking tools
  • P243 Take precautionary measures against static discharge.
  • P261 Avoid breathing dust / fume / gas / mist / vapors / spray.
  • P262 Do not get in eyes, on skin, or on clothing.
  • P264 Wash thoroughly after handling.
  • P272 Contaminated work clothing should not be allowed out of the workplace.
  • P273 Avoid release to the environment.
  • P280 Wear protective gloves / eye protection / face protection.
  • [RESPONSE]:
  • P301+310 IF SWALLOWED: Immediately call a POISON CENTER or doctor / physician.
  • P302+352 IF ON SKIN: Wash with plenty of soap and water.
  • P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present andeasy to do - continue rinsing.
  • P313 Get medical advice / attention.
  • P321 Specific treatment (see information on this label).
  • P331 Do NOT induce vomiting.
  • P333+313 If skin irritation or a rash occurs: Get medical advice / attention.
  • P337+313 If eye irritation persists: Get medical advice / attention.
  • P362 Take off contaminated clothing and wash before reuse.
  • P363 Wash contaminated clothing before reuse.
  • P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction.
  • P391 Collect spillage.
  • [STORAGE]:
  • P403+233 Store in a well ventilated place. Keep container tightly closed.
  • [DISPOSAL]:
  • P501 Dispose of contents / container in accordance with local / national regulations.

III. COMPOSITION / INFORMATION ON INGREDIENTS

This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.


Ingredient/Chemical Designations Weight % GHS Classification Notes
Aliphatic Hydrocarbon CAS Number: 0064742-49-0 25 - 50 Asp. Tox. 1;H304 [1]
Petroleum Resin CAS Number: 0064742-16-1 10 - 25 Acute Tox. 4;H302 [1]
Titanium dioxide CAS Number: 0013463-67-7 1.0 - 10 Not Classified [1][2]
BENZENE, ETHENYL-, POLYMER WITH 1,3-BUTADIENE, HYD
CAS Number: 0066070-58-4
1.0 - 10 Aquatic Chronic 4;H413 [1]
Xylene CAS Number: 0001330-20-7 1.0 - 10 Flam. Liq. 3;H226
Acute Tox. 4;H332
Acute Tox. 4;H312
Skin Irrit. 2;H315
[1][2]
Calcium carbonate CAS Number: 0001317-65-3 1.0 - 10 Not Classified [1][2]
2-N-octyl-4-isothiazoline-3-one CAS Number: 0026530-20-1 0.10 - 1.0 Acute Tox. 3;H331 Acute Tox. 3;H311
Acute Tox. 4;H302 Skin Corr. 1B;H314
Skin Sens. 1;H317 (@>0.05%)
Aquatic Acute 1;H400 Aquatic Chronic 1;H410
[1]

In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret. [1] Substance classified with a health or environmental hazard. [2] Substance with a workplace exposure limit. *The full texts of the phrases are shown in Section 16

IV. FIRST-AID MEASURES

  • General
  • In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
  • Inhalation
  • Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.
  • Eyes
  • Flush with water and remove contact lenses. Continue to flush eyes with large amounts of water for 15 minutes. Get medical attention immediately.
  • Ingestion
  • If swallowed do not give anything to drink. Do not induce vomiting except under physician’s instruction. Get medical attention immediately. Never give anything by mouth to an unconscious person.
  • Effects of Overexposure
  • Inhalation: Breathing large amounts of vapors or mists may be harmful. Symptoms include central nervous system excitement (giddiness, liveliness) followed by central nervous system depression (fatigue, dizziness, drowsiness, nausea, headache). Prolonged exposure may cause liver and kidney damage.
  • Eyes: May cause mild eye irritation such as stinging, redness, & tearing.
  • Skin: May be absorbed through the skin and cause skin irritation. Prolonged or repeated contact may dry the skin resulting in skin irritation and dermatitis.
  • Ingestion: Moderately toxic. Swallowing large amounts may be harmful or fatal with central nervous system effects, which can include dizziness, loss of balance and coordination,unconsciousness, coma and even death.
  • Exposure to solvent vapor concentrations from the component solvents in excess of thestated occupational exposure limits may result in adverse health effects such as mucousmembrane and respiratory system irritation and adverse effects on the kidneys, liver andcentral nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscularweakness, drowsiness and in extreme cases, loss of consciousness.
  • Repeated or prolonged contact with the preparation may cause removal of natural fat fromthe skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solventsmay also be absorbed through the skin. Splashes of liquid in the eyes may cause irritationand soreness with possible reversible damage. See section 2 for further details.
  • Causes serious eye irritation.
  • May cause an allergic skin reaction. Causes skin irritation

V. FIRE-FIGHTING MEASURES

  • Extinguishing media
  • Water, carbon dioxide, foam or dry powder.
  • Special hazards arising from the substance or mixture
  • Keep away from heat / sparks / open flames / hot surfaces - No smoking.
  • Hazardous decomposition: High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide.
  • Keep cool
  • Ground / bond container and receiving equipment.
  • Use explosion-proof electrical / ventilating / light / equipment.
  • Use only non-sparking tools.
  • Take precautionary measures against static discharge.
  • Avoid breathing dust / fume / gas / mist / vapors / spray.
  • Advice for fire-fighters
  • Do not mix with strong oxidizers such as liquid chlorine or concentrated oxygen.
  • Do not get in eyes, on skin, or on clothing.
  • Wear SCBA with full-face piece operating in a positive pressure demand mode and full protective gear.
  • ERG Guide No. 127

VI. ACCIDENTAL RELEASE MEASURES

  • Personal precautions, protective equipment and emergency procedures
  • Put on appropriate personal protective equipment (see section 8).
  • Environmental precautions
  • Do not allow spills to enter drains or waterways.
  • Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
  • Methods and material for containment and cleaning up
  • Shut off ignition sources including electrical equipment and flames. Contain spilled material. Absorb spills with inert material such as vermiculite, dry sand or earth. Place in a closed container but do not seal. Ventilate area to remove vapors.
  • Disposal should be in accordance with local, state, and federal regulations. The preferred method of liquid waste is incineration. Cured, solid waste is considered non-hazardous and may be land filled if allowed. Keep all waste from entering sewers, drains or waterways.

VII. HANDLING AND STORAGE

  • Precautions for safe handling
  • Avoid prolonged or repeated skin contact. Avoid breathing aerosols, spray mists, and heated vapors. Use only in wellventilated area. Use good personal and industrial hygiene practices.
  • Keep container closed after each use.
  • See section 2 for further details. - [Prevention]:
  • Conditions for safe storage, including any incompatibilities
  • Handle containers carefully to prevent damage and spillage
  • Incompatible materials: Contact with water will cause this product to cure. Incompatible with acids, bases, andoxidizers
  • Recommended storage range is less than 90°F.
  • See section 2 for further details. - [Storage]:

VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION

CAS NoIngredientSourceValue
0001330-20-7 XyleneOSHASTEL 150 ppm
ACGIHTWA: 100 ppm STEL: 150 ppm
  • Respiratory If workers are exposed to concentrations above the exposure limit they must use theappropriate, certified respirators.
  • Eyes Chemical splash goggles (ANSI Z-87.1 or approved equivalent) and/or face shield. Have an eye wash station available.
  • Skin Avoid all skin contact by covering as much of the exposed skin area as possible withappropriate clothing. Wear impervious gloves.
  • Engineering Controls Provide adequate ventilation. Where reasonably practicable this should be achieved by theuse of local exhaust ventilation and good general extraction. If these are not sufficient tomaintain concentrations of particulates and any vapor below occupational exposure limitssuitable respiratory protection must be worn.
  • Other Work Practices Use good personal hygiene practices. Wash hands before eating, drinking, smoking orusing toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
  • See section 2 for further details. - [Prevention]:

IX. PHYSICAL AND CHEMICAL PROPERTIES

  • Appearance Viscous Liquid
  • Odor Not specified
  • Odor threshold Not determined
  • pH Not available
  • Melting point / freezing point Not applicable
  • Initial boiling point and boiling range 281 - 284°F
  • Flash Point 68°F
  • Evaporation rate (Ether = 1) Slower than ether
  • Flammability (solid, gas) Not Applicable
  • Upper/lower flammability or explosive limits: Lower Explosive Limit: 1% Upper Explosive Limit: 7%
  • Vapor pressure (Pa) Not established
  • Vapor Density Not available
  • Specific Gravity Not available
  • Solubility in Water Insoluble
  • Partition coefficient n-octanol/water (Log Kow) Not Measured
  • Auto-ignition temperature Not established
  • Decomposition temperature Not available
  • Viscosity (cSt) 50,000 - 90,000 cps
  • VOC Content less than 500 g/liter
  • Density 7.4 - 7.8 pounds per gallon
  • % Volatile 53 - 57% (by volume)
  • Other information No other relevant information

X. STABILITY AND REACTIVITY

  • Reactivity May polymerize
  • Chemical stability Stable under normal circumstances
  • Possibility of hazardous reactions Reaction with water can create CO2.
  • Conditions to avoid Excessive heat and open flame.
  • Incompatible materials Contact with water will cause this product to cure. Incompatible with acids, bases, and oxidizers
  • Hazardous decomposition products High temperatures and fires may produce such toxic substances as carbon monoxide and carbon dioxide.

XI. TOXICOLOGICAL INFORMATION

  • Acute toxicity Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposurelimits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverseeffects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue,muscular weakness, drowsiness and in extreme cases, loss of consciousness.
  • Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin.Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.
Ingredient Oral LD50, mg/kgSkin LD50, mg/kgInhalation Vapor LC50, mg/L/4hrInhalation Dust/Mist LC50, mg/L/4hrInhalation Gas LC50, ppm
Aliphatic Hydrocarbon - (64742-49-0) 5,000.00, Rat - Category: 53,160.00, Rabbit - Category: 5No data availableNo data availableNo data available
Petroleum Resin - (64742-16-1) 2,000.00, Mammal - Category: 4No data availableNo data availableNo data availableNo data available
Titanium dioxide - (13463-67-7) 10,000.00, Rat - Category: NA10,000.00, Rabbit - Category: NANo data available6.82, Rat - Category: NANo data available
Alkyl quaternary ammonium bentonite - (68953-58- 2)5,000.00, Rat - Category: 5No data availableNo data available12.60, Rat - Category: NANo data available
Xylene - (1330-20-7)4,299.00, Rat - Category: 51,548.00, Rabbit - Category: 4No data available20.00, Rat - Category: NA5,000.00, Rat - Category: 4
2-N-octyl-4-isothiazoline-3-one - (26530-20-1)550.00, Rat - Category: 4690.00, Rabbit - Category: 3No data available0.27, Rat - Category: 2No data available
  1. Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimatewas used in the calculation of the product's ATE (Acute Toxicity Estimate).

Carcinogen Data

CAS No.IngredientSourceValue
0001330-20-7XyleneIARCGroup 3: Yes
0013463-67-7Titanium dioxideIARCGroup 2b: Yes

XII. ECOLOGICAL INFORMATION

  • Toxicity
  • Toxic to aquatic life with long lasting effects
  • No additional information provided for this product. See Section 3 for chemical specific data.
Ingredient 96 hr LC50 fish, mg/l48 hr EC50 crustacea, mg/lErC50 algae, mg/l
Aliphatic Hydrocarbon - (64742-49-0)Not Available 2.60, Chaetogammarus marinusNot Available
Titanium dioxide - (13463-67-7)1,000.00, Fundulus heteroclitus5.50, Daphnia magna5.83 (72 hr), Pseudokirchneriella subcapitata
Xylene - (1330-20-7)3.30, Oncorhynchus mykiss8.50, Palaemonetes pugio100.00 (72 hr), Chlorococcales
2-N-octyl-4-isothiazoline-3-one - (26530-20-1)0.0555, Oncorhynchus mykiss0.18, Daphnia magna0.084 (72 hr), Scenedesmus subspicatus
  • Persistence and degradability
  • There is no data available on the preparation itself.
  • Bioaccumulative potential
  • Not Measured
  • Mobility in soil
  • No data available.
  • Results of PBT and vPvB assessment
  • This product contains no PBT/vPvB chemicals.
  • Other adverse effects
  • No data available.

XIII. DISPOSAL CONSIDERATIONS

  • Waste treatment methods
  • Observe all federal, state and local regulations when disposing of this substance.

XIV. TRANSPORT INFORMATION

DOT (Domestic Surface Transportation)IMO / IMDG (Ocean Transportation)ICAO/IATA
UN numberUN1263 UN1263UN1263
UN proper shipping nameUN1263, Paint, 3, III Paint Paint
Transport hazard class(es)DOT Hazard Class: 3IMDG: 3 Sub Class: Not ApplicableAir Class: 3
Packing groupIIIIIIIII
Environmental hazards
IMDG Marine Pollutant: Yes ( Aliphatic Hydrocarbon )
  • Special precautions for user
  • No further information

XV. REGULATORY INFORMATION

  • Regulatory Overview The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented.
  • Toxic Substance Control Act ( TSCA)All components of this material are either listed or exempt from listing on the TSCA Inventory
  • WHMIS Classification B2 D2B
  • US EPA Tier II Hazards
  • Fire: Yes
  • Sudden Release of Pressure: No
  • Reactive: No
  • Immediate (Acute): Yes
  • Delayed (Chronic): No
  • EPCRA 311/312 Chemicals and RQs (lbs):
  • Xylene ( 100.00)
  • EPCRA 302 Extremely Hazardous:
  • To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • EPCRA 313 Toxic Chemicals:
  • Ethyl Benzene, Xylene
  • Proposition 65 - Carcinogens (>0.0%):
  • Ethyl Benzene, Titanium dioxide
  • Proposition 65 - Developmental Toxins (>0.0%):
  • To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • Proposition 65 - Female Repro Toxins (>0.0%):
  • To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • Proposition 65 - Male Repro Toxins (>0.0%):
  • To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • New Jersey RTK Substances (>1%):
  • Calcium carbonate, Titanium dioxide, Xylene
  • Pennsylvania RTK Substances (>1%):
  • Calcium carbonate, Titanium dioxide, Xylene

XVI. OTHER INFORMATION

This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.