- PRODUCT IDENTIFICATION
- PrimeLock Rust Primer
- Packaging: pails
- CAS Number: n/a
- DATE UPDATED: Thursday, May 10, 2018
- EMERGENCY TELEPHONE NUMBER: INFOTRAC: 800-535-5053
II. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Skin Irrit. 2;H315: Causes skin irritation.
Eye Irrit. 2;H319: Causes serious eye irrtation.
Skin Sens. 1;H317: May cause an allergic skin reaction.
Using the Toxicity Data listed in section 11 and 12 the product is labeled as follows.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
P261 Avoid breathing dust / fume / gas / mist / vapors / spray.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves / eye protection / face protection.
P302+352 IF ON SKIN: Wash with plenty of soap and water.
P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.
P313 Get medical advice / attention.
P321 Specific treatment (see information on this label).
P333+313 If skin irritation or a rash occurs: Get medical advice / attention.
P337+313 If eye irritation persists: Get medical advice / attention.
P362 Take off contaminated clothing and wash before reuse.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
No GHS storage statements
P501 Dispose of contents / container in accordance with local / national regulations.
III. COMPOSITIONS / INFORMATION ON INGREDIENTS
This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.
|Ingredient/Chemical Designations ||Weight % ||GHS Classification ||Notes |
|Zinc phosphate ||10 - 25 ||Aquatic Acute 1;H400 |
Aquatic Chronic 1;H410
CAS Number: 0026530-20-1
|0.10 - 1.0 |
|Acute Tox. 3;H331 |
Acute Tox. 3;H311
Acute Tox. 4;H302
Skin Corr. 1B;H314
Skin Sens. 1;H317 (@>0.05%)
Aquatic Acute 1;H400
Aquatic Chronic 1;H410
In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.
 Substance classified with a health or environmental hazard.
*The full texts of the phrases are shown in Section 16.
IV. FIRST AID MEASURES
- Description of first aid measures
- General: In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
- Inhalation: Remove to fresh air, keep patient warm and at rest. If breathing is irregular or stopped, give artificial respiration. If unconscious place in the recovery position and obtain immediate medical attention. Give nothing by mouth.
- Eyes: Irrigate copiously with clean water for at least 15 minutes, holding the eyelids apart and seek medical attention.
- Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water or use a recognized skin cleanser.
- Ingestion: If swallowed give two glasses of water to drink. Do not induce vomiting. Get medical attention immediately. Never give anything by mouth to an unconscious person.
- Most important symptoms and effects, both acute and delayed
- Overview Effects of Overexposure:
- Inhalation: Spray mist in poorly ventilated areas can cause headache, nausea and irritation of the nose, throat, & lungs.
- Eyes: Direct contact may cause irritation.
- Skin: May cause moderate skin irritation with repeated contact.
- See section 2 for further details.
- Eyes: Causes serious eye irritation.
- Skin: May cause an allergic skin reaction. Causes skin irritation.
V. FIRE-FIGHTING MEASURES
- Extinguishing media: Water, carbon dioxide, foam or dry powder.
- Special hazards arising from the substance or mixture: Hazardous decomposition: Acrylic monomersAvoid breathing dust / fume / gas / mist / vapors / spray.
- Advice for fire-fighters: Wear SCBA and full protective gear when entering a confined or enclosed space to protect from normal combustion products and/or oxygen deficiency.
- ERG Guide No.: ----
VI. ACCIDENTIAL RELEASE MEASURES
- Personal precautions, protective equipment and emergency procedures: Put on appropriate personal protective equipment (see section 8).
- Environmental precautions: Do not allow spills to enter drains or waterways.Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
- Methods and material for containment and cleaning up: Keep spectators away as the floor may be slippery. Use care to avoid falling. Keep spills out of municipal sewers and open bodies of water. Dike and contain spill with inert material such as dry sand or earth. Transfer liquid material to a suitable container for recovery or disposal.
VII. HANDLING ADN STORAGE
- Precautions for safe handling: Keep from freezing.See section 2 for further details. - [Prevention]:
- Conditions for safe storage, including any incompatibilities: Handle containers carefully to prevent damage and spillage.Incompatible materials: No known incompatible materials for this product.Recommended storage range is 45 - 90°F. Keep container tightly closed.See section 2 for further details. - [Storage]:
- Specific end use(s): No data available.
VIII. EXPOSURE CONTROLS AND PERSONAL PROTECTION
- Control parameters Exposure
- Exposure controls
- Respiratory: If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.
- Eyes: Chemical splash goggles (ANSI Z-87.1 or approved equivalent)
- Skin: Chemical impervious gloves required.
- Engineering Controls: Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.
- Other Work Practices: Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.See section 2 for further details. - [Prevention]:
IX. PHYSICAL AND CHEMICAL PROPERTIES
|Appearance ||Milky white, gray or black Liquid Not Specified |
|Odor ||Not Specified |
|Odor threshold ||Not Measured |
|pH ||Not available |
|Melting point / freezing point |
|0°C (32°F) |
|Initial boiling point and boiling range ||100°C (212°F) |
|Flash Point ||Non-combustible |
|Evaporation rate (Ether = 1) ||Less than 1 (n-BuAc = 1) |
|Flammability (solid, gas) ||Not Applicable |
|Upper/lower flammability or explosive limits ||Lower Explosive Limit: Not applicable |
| ||Upper Explosive Limit: Not applicable |
|Vapor pressure (Pa) ||Greater than 1 |
|Vapor Density ||Not available |
|Specific Gravity ||Not available |
| Solubility in Wate ||Dispersible |
|Partition coefficient n-octanol/water (Log Kow) ||Not Measured |
|Auto-ignition temperature ||Not applicable |
|Decomposition temperature ||Not available |
|Viscosity (cSt) ||500 - 1100 cps |
|VOC Content ||Less than 35 g/liter |
|Density ||8.8 - 9.2 pounds per gallon |
|% Volatile ||66 - 70% (by volume)|
No other relevant information.
X. STABILITY AND REACTIVITY
- Reactivity: Hazardous Polymerization will not occur.
- Chemical stability: Stable under normal circumstances.
- Possibility of hazardous reactions: No data available.
- Conditions to avoid: No data available.
- Incompatible materials: No known incompatible materials for this product.
- Hazardous decomposition products: Acrylic monomers
XI. TOXICOLOGICAL INFORMATION
|Ingredient||Oral LD50, mg/kg||Skin LD50, mg/kg||Inhalation Vapor LC50, mg/L/4hr||Inhalation Dust/Mist LC50, mg/L/4hr||Inhalation Gas LC50, ppm|
|Zinc phosphate - (7779-90-0)||> 5,000.00, Rat - Category: NA||No data available||No data available||No data available||No data available|
|2-N-octyl-4-isothiazoline-3-one - (26530-20-1)||550.00, Rat - Category: 4||690.00, Rabbit - Category: 3||No data available||0.27, Rat - Category: 2||No data available|
Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).
XII. ECOLOGICAL INFORMATION
Very toxic to aquatic life with long lasting effects.
No additional information provided for this product. See Section 3 for chemical specific data.
|Ingredient||96 hr LC50 fish, mg/l||48 hr EC50 crustacea, mg/l||ErC50 algae, mg/l|
|Zinc phosphate - (7779-90-0)||0.09, Oncorhynchus mykiss||0.04, Daphnia magna||0.136 (72 hr), Selenastrum capricornutum|
|2-N-octyl-4-isothiazoline-3-one - (26530-20-1)||0.0555, Oncorhynchus mykiss||0.18, Daphnia magna||0.084 (72 hr), Scenedesmus subspicatus|
- Persistence and degradability: There is no data available on the preparation itself.
- Bioaccumulative potential: Not Measured
- Mobility in soil: No data available.
- Results of PBT and vPvB assessment: This product contains no PBT/vPvB chemicals.
- Other adverse effects: No data available.
XIII. DISPOSAL CONSIDERATIONS
Waste treatment methods
Observe all federal, state and local regulations when disposing of this substance.
XIV. TRANSPORT INFORMATION
|DOT (Domestic Surface Transportation)||IMO / IMDG (Ocean Transportation||ICAO/IATA|
|UN number||Not Applicable||Not Regulated||Not Regulated|
|UN proper shipping name||Not Regulated||Not Regulated||Not Regulated|
|Transport hazard class(es)||DOT Hazard Class: Not Applicable||IMDG: Not Applicable||Air Class: Not Applicable|
|Sub Class: Not Applicable|
|Packing group||Not Applicable||Not Applicable||Not Applicable|
|IMDG||Marine Pollutant: Yes (Zinc phosphate)|
|Special precautions for user||No further information|
XV. REGULATORY INFORMATION
- Regulatory Overview: The regulatory data in Section 15 is not intended to be all-inclusive, only selected regulations are represented.
- Toxic Substance Control Act ( TSCA): All components of this material are either listed or exempt from listing on the TSCA Inventory.
- WHMIS Classification: D2B
- US EPA Tier II Hazards: Fire: No , Sudden Release of Pressure: No, Reactive: No, Immediate (Acute): Yes, Delayed (Chronic): No
- EPCRA 311/312 Chemicals and RQs: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- EPCRA 302 Extremely Hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- EPCRA 313 Toxic Chemicals: Zinc phosphate
- Proposition 65 - Carcinogens (>0.0%): Regulatory dddddTitanium dioxide
- Proposition 65 - Developmental Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- Proposition 65 - Female Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- Proposition 65 - Male Repro Toxins (>0.0%): To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- New Jersey RTK Substances (>1%) : To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
- Pennsylvania RTK Substances (>1%) : To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
XVI. OTHER INFORMATION
This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.