EnergyGuard Silicone Coating SDS

Safety Data Sheet

I. IDENTIFICATION

PRODUCT IDENTIFICATION
EnergyGuard Silicone Coating
Packaging: pails, drums
CAS Number: Mixture
DATE UPDATED
Thursday, May 10, 2018
EMERGENCY TELEPHONE NUMBER
CHEMTREC: 800-424-9300 (US) 1(202)483-7616 (International)
SUPPLIER INFORMATION

II. HAZARDS(S) IDENTIFICATION

Classification of the substance or mixture

  • Flam. Liq. 2;H226
  • Skin Irrit. 3;H316
  • Eye Irrit. 2;H319
  • Skin Sens. 1;H317
  • Carc. 2;H351

Label elements

in section 11 and 12 the product is labeled as follows.

Hazard Pictograms
  • Harmful
    Harmful
  • Flammable
    Flammable
  • Health Hazard
    Health Hazard

H226 Combustible liquid.
H316 Causes mild skin irritation.
H317 May cause an allergic skin reaction. H319 Causes serious eye irritation.
H351 Suspected of causing cancer.

[Prevention]:

P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat / sparks / open flames / hot surfaces - No smoking. P235 Keep cool.
P240 Ground / bond container and receiving equipment.
P241 Use explosion-proof electrical / ventilating / light / equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing dust / fume / gas / mist / vapors / spray.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves / eye protection / face protection.

[Response]:

P302+352 IF ON SKIN: Wash with plenty of soap and water.

P303+361+353 IF ON SKIN (or hair): Remove / Take off immediately all contaminated clothing. Rinse skin with water / shower.

P305+351+338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

P308+313 IF exposed or concerned: Get medical advice / attention.
P321 Specific treatment (see information on this label).
P333+313 If skin irritation or a rash occurs: Get medical advice / attention. P337+313 If eye irritation persists: Get medical advice / attention.

P363 Wash contaminated clothing before reuse.
P370+378 In case of fire: Use extinguishing media listed in section 5 of SDS for extinction.

[Storage]:

P403+233 Store in a well ventilated place. Keep container tightly closed. P405 Store locked up.

[Disposal]:

P501 Dispose of contents / container in accordance with local / national regulations.

III. COMPOSITION / INFORMATION ON INGREDIENTS

This product contains the following substances that present a hazard within the meaning of the relevant State and Federal Hazardous Substances regulations.

Ingredient/Chemical Designations

Weight %

GHS Classification

Notes

Petroleum distillates, hydrotreated light CAS Number: 0064742-47-8

10 - 25

Asp. Tox. 1;H304

[1]

Methyltris(methylethylketoximino)silane CAS Number: 0022984-54-9

1.0 - 10

Eye Irrit. 2;H319 Skin Irrit. 2;H315 Skin Sens. 1;H317

[1]

2-Butanone oxime
CAS Number: 0000096-29-7

1.0 - 10

Carc. 2;H351 Acute Tox. 4;H312 Eye Dam. 1;H318 Skin Sens. 1;H317

[1]

Proprietary*

0.10 - 1.0

Skin Irrit. 2;H315
Eye Irrit. 2;H319
Skin Sens. 1;H317 Aquatic Chronic 3;H412

[1]

*In accordance with paragraph (i) of §1910.1200, the specific chemical identity and/or exact percentage (concentration) of composition has been withheld as a trade secret.
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] PBT-substance or vPvB-substance.


IV. FIRST-AID MEASURES

Most important symptoms and effects, both acute and delayed

Overview

Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness..

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.

Possible cancer hazard. Contains an ingredient which may cause cancer based on animal data (See Section 3 and Section 15 for each ingredient). Risk of cancer depends on duration and level of exposure.

See section 2 for further details.
  • Eyes: Causes serious eye irritation.
  • Skin: May cause an allergic skin reaction. Causes mild skin irritation. (Not adopted by US OSHA)

V. FIRE-FIGHTING MEASURES

5.1. Extinguishing media

Foam, dry chemical, CO2, water

5.2. Special hazards arising from the substance or mixture

Hazardous decomposition: High temperatures and fires may produce carbon monoxide, oxides of nitrogen and various hydrocarbon fragments.

Keep away from heat / sparks / open flames / hot surfaces - No smoking. Keep cool.
Ground / bond container and receiving equipment.
Use explosion-proof electrical / ventilating / light / equipment.

Use only non-sparking tools.
Take precautionary measures against static discharge. Avoid breathing dust / fume / gas / mist / vapors / spray. 5.3. Advice for fire-fighters

If electrical equipment is involved, the use of foam should be avoided. Use water spray to cool non-involved containers.
Wear SCBA with a full-face piece operated in the positive pressure demand mode and full protective clothing (Bunker Gear) when fighting fires.

ERG Guide No. 127

VI. ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

Put on appropriate personal protective equipment (see section 8).

6.2. Environmental precautions

Do not allow spills to enter drains or waterways.

Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.

6.3. Methods and material for containment and cleaning up

Small spill: Remove with absorbent material.

Large spill: Eliminate all ignition sources. Ventilate enclosed areas or wear self-contained breathing apparatus. Recover free liquid in closed containers. Keep out of sewers and water courses. Clean area with absorbent material.

VII. HANDLING AND STORAGE

7.1. Precautions for safe handling

Protect from freezing.

See section 2 for further details. - [Prevention]:

7.2. Conditions for safe storage, including any incompatibilities

Handle containers carefully to prevent damage and spillage.

Naked flames and smoking should not be permitted in storage areas. It is recommended that fork lift trucks and electrical equipment are protected to the appropriate standard.

Incompatible materials: Avoid strong oxidizing agents, concentrated nitric and sulfuric acids, halogen, and molten sulfur.

Store in a cool, dry place. Keep container tightly closed when not in use. See section 2 for further details. - [Storage]:


7.3. Specific end use(s)
No data available.

VIII. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1. Control parameters Exposure

Exposure

CAS No.

Ingredient

Source

Value

0064742-47-8

Petroleum distillates, hydrotreated light

Supplier

Recommended 300 ppm PEL

8.2. Exposure controls

  • Respiratory: If workers are exposed to concentrations above the exposure limit they must use the appropriate, certified respirators.
  • Eyes: Not needed under normal circumstances.
  • Skin: Not needed under normal circumstances. protective gloves as needed to avoid skin irritation.
  • Engineering Controls: Provide adequate ventilation. Where reasonably practicable this should be achieved by the use of local exhaust ventilation and good general extraction. If these are not sufficient to maintain concentrations of particulates and any vapor below occupational exposure limits suitable respiratory protection must be worn.
  • Other Work Practices: Use good personal hygiene practices. Wash hands before eating, drinking, smoking or using toilet. Promptly remove soiled clothing and wash thoroughly before reuse.
  • See section 2 for further details. - [Prevention]:

IX. PHYSICAL AND CHEMICAL PROPERTIES

  • Appearance: Viscous white or gray Liquid
  • Odor: petroleum odor
  • Odor threshold:  Not Measured
  • pH: Not available
  • Melting point / freezing point: Not determined
  • Initial boiling point and boiling range:  310 - 385°F
  • Flash Point:  > 105°F TCC method
  • Evaporation rate (Ether = 1)Flammability (solid, gas): Slower than ether
  • Flammability (solid, gas): Not Applicable
  • Upper/lower flammability or explosive limits:  Lower Explosive Limit: 1.1 Upper Explosive Limit: 5.0
  • Vapor pressure (Pa): Not determined
  • Vapor Density:  Not available
  • Specific Gravity: 1.23 (H2O = 1)
  • Solubility in Water: Negligible
  • Partition coefficient n-octanol/water (Log Kow):  Not Measured
  • Auto-ignition temperature:  Not available
  • Decomposition temperature:  Not available
  • Viscosity:  4000 cps
  • VOC Content:  <250 g/liter
  • Density: Heavier than air (air + 1)

9.2. Other information
No other relevant information.

X.  STABILITY AND REACTIVITY

10.1. Reactivity
Hazardous Polymerization will not occur.

10.2. Chemical stability
Stable under normal circumstances.

10.3. Possibility of hazardous reactions
No data available.

10.4. Conditions to avoid
Excessive heat and open flame.

10.5. Incompatible materials
Avoid strong oxidizing agents, concentrated nitric and sulfuric acids, halogen, and molten sulfur.

10.6. Hazardous decomposition products
High temperatures and fires may produce carbon monoxide, oxides of nitrogen and various hydrocarbon fragments.

XI. TOXICOLOGICAL INFORMATION

Exposure to solvent vapor concentrations from the component solvents in excess of the stated occupational exposure limits may result in adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liver and central nervous system. Symptoms include headache, nausea, dizziness, fatigue, muscular weakness, drowsiness and in extreme cases, loss of consciousness.

Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin resulting in dryness, irritation and possible non-allergic contact dermatitis. Solvents may also be absorbed through the skin. Splashes of liquid in the eyes may cause irritation and soreness with possible reversible damage.

Ingredient

Oral LD50, mg/kg

Skin LD50, mg/kg

Inhalation Vapor LC50, mg/L/4hr

Inhalation Dust/Mist LC50, mg/L/4hr

Inhalation Gas LC50, ppm

Petroleum distillates, hydrotreated light - (64742-47-8)

> 5,000.00, Rat - Category:

NA

No data available

No data available

No data available

No data available

Methyltris(methylethylketoximino)silane - (22984-54-9)

No data available

No data available

No data available

No data available

No data available

2-Butanone oxime - (96-29-7)

930.00, Rat - Category: 4

2,000.00, Rabbit -

Category: 4

20.00, Rat - Category: 4

No data available

5,000.00, Rat - Category: 4

(Trimethoxysilylpropyl)ethylenediamine - (1760-24-3)

7,684.00, Rat - Category: NA

No data available

No data available

No data available

No data available

Note: When no route specific LD50 data is available for an acute toxin, the converted acute toxicity point estimate was used in the calculation of the product's ATE (Acute Toxicity Estimate).

XII. ECOLOGICAL INFORMATION

12.1. Toxicity
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive 1999/45/EC and GHS and is not classified as dangerous for the environment, but contains substance(s) dangerous for the environment. See section 3 for details

Aquatic Ecotoxicity

Ingredient

96 hr LC50 fish, mg/l

48 hr EC50 crustacea, mg/l

ErC50 algae, mg/l

Quartz (non respirable) - (14808-60-7)

Not Available

Not Available

Not Available

Petroleum distillates, hydrotreated light - (64742-47-8)

45.00, Pimephales promelas

4,720.00, Dendronereides heteropoda

Not Available

2-Butanone oxime - (96-29-7)

320.00, Leuciscus idus

500.00, Daphnia magna

83.00 (72 hr), Scenedesmus subspicatus

(Trimethoxysilylpropyl)ethylenediamine - (1760-24-3)

597.00, Danio rerio

81.00, Daphnia magna

126.00 (72 hr), Scenedesmus subspicatus

12.2. Persistence and degradability
There is no data available on the preparation itself.

12.3. Bioaccumulative potential
Not Measured

12.4. Mobility in soil
No data available.

12.5. Results of PBT and vPvB assessment
This product contains no PBT/vPvB chemicals.

12.6. Other adverse effects
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Potentially toxic to aquatic life.

XIII. DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods
Observe all federal, state and local regulations when disposing of this substance.

XIV. TRANSPORT INFORMATION

DOT (Domestic Surface Transportation)IMO / IMDG (Ocean Transportation)ICA/IATA
14.1 UN numberNot ApplicableNot RegulatedNot Regulated
14.2 UN proper shipping nameNot RegulatedNot RegulatedNot Regulated
14.3 Transport hazard class(es)DOT Hazard Class: Not ApplicableIMDG: Not ApplicableAir Class: Not Applicable
Sub Class: No Applicable
14.4 Packing groupNot ApplicableNot ApplicableNot Applicable
14.5 Environmental hazards
IMDGMariner Pollutant: No
14.6 Special precautions for userNo further information

XV. REGULATORY INFORMATION

  • Regulatory Overview: The regulatory data in Section 15 is regulations are represented.
  • Toxic Substance Control Act ( TSCA): All components of this material are either listed or exempt from listing on the TSCA Inventory.
  • WHMIS Classification: B3 D2A
  • US EPA Tier II Hazards:
      Fire: Yes
      Sudden Release of Pressure: No
      Reactive: No
      Immediate (Acute): Yes
      Delayed (Chronic): Yes
  • EPCRA 311/312 Chemicals and RQs: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • EPCRA 302 Extremely Hazardous: To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • EPCRA 313 Toxic Chemicals:
  • To the best of our knowledge, there are no chemicals at levels which require reporting under this statute.
  • California Proposition 65 - Carcinogens (>0.0%)
  • This product may contain trace amounts of benzene, ethyl benzene and toluene which are known by the State of California to cause cancer, birth defects or other reproductive harm.

XVI. OTHER INFORMATION

The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, expressed or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to our products. Customers/users of this product must comply with all applicable health and safety laws, regulations, and orders.

This is the first version in the GHS SDS format. Listings of changes from previous versions in other formats are not applicable.

Judgments as to the suitability of information herein for the purchaser’s purposes are necessarily the purchaser’s responsibility. Although reasonable care has been taken in the preparation of such information, Aldo Products Company, extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to the purchaser’s intended purpose or for consequences of its use.

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.